It is the simplest and smallest ketone.It is a colourless, highly volatile and flammable liquid with a characteristic pungent odour. VOC-containing products. Check the EDS or other technical data to see if the coating contains water and exempt solvents and if the VOC content is expressed as lbs VOC/gal., minus water and exempt solvents, or lbs/gal less exempt solvents. “VOC-exempt” refers to a solvent that is on the VOC-exempt lists maintained by the EPA and SCAQMD. The original definition of VOC made reference to the vapor pressure of the Cyclo-2245 VOC Exempt Solvent/ VOC Exempt Carrying Agent Decamethylcyclopentasiloxane (Cyclomethicone) Products Description: VOC Exempt Solvents/ Carrying agents are Cyclic Silicone fluids that are exempt from federal VOC regulations including California (CARB) regulations and OTC regulations. Several widely used exempt VOCs include, but are not limited to, acetone, methyl acetate, t … Carbo-Sol was discontinued in January, 2006 because of changes in air pollution regulations in California and other states. ” Fast dry ” No residue ” 100% Pure. From a legal standpoint, the “regulatory VOC” can be found using the formula: VOC regulatory = grams of VOC / ( L paint – L water – L exempts) Notice that VOC exempt compounds are not included with this calculation, which means that paint companies are free to formulate coatings with exempt solvents in order to minimize the VOC profile. In coating materials of less than 1 pound of solids per gallon the material VOC is used. Acetone (67- 64 -1) No No None 12. Acetone is miscible in water. In 1999, when Environment Canada added VOCs to the list of toxic substances in CEPA Schedule 1, it listed 44 exempt com-pounds identical to the U.S. list of VOC-exempt compounds. The weight ratio of acetone to PCBTF in automotive refinish formulations in California is on the order of 1:2. Only single component solvents that have been found not to contribute to ground level smog may be classified as VOC-exempt. simple ORM-D shipping, vs. the much more strict, costly, and controlled "hazmat" shipping). It is used as a volatile component of some paints and varnishes. Overall Weight of VOC – Each component in the bucket has a specific weight of VOC in it. This exemption will enable product The VOC of Mixture is most easily understood if you picture a bucket of the mixed coating. Calculating VOC Emissions using Mass Balance Amount of Coating Used – 4,000 gallons VOC Content – 2.11 lbs/gallon 4,000 gallons x 2.11 lbs/gallon = 8,440 lbs of VOC These companies offer a comprehensive range of Acetone, as well as a variety of related products and services. Acetone and PCBTF are currently the primary compliance solvents for low-VOC 2K urethane coatings and equipment cleanup. Click on company profile for additional company and contact information. UPS Hazarous handling charge will be added to shipping charge. Acetone; EkaSol 1 is considered Zero-VOC in 49 states and parts of California because it is comprised only of materials listed by the EPA in section 40 CFR 51.100(s) index in the United States. This list of compounds (often referred to as “VOC-exempt compounds”) is established and modified by regulation. VOCs (volatile organic compounds) are found in wide variety of everyday products such as solvent-based paints/coatings, adhesives, sealants, printing inks, many consumer products, organic solvents and petroleum products. There are no non-exempt VOC emissions from the cleanup process. Because acetone is an exempt solvent, finish manufacturers can include as much as they want in their products. Hazardous Information: UN: 1090; ERG: 127; Class: 3; Packing Group: II; Applications. For example, acetone is a VOC-exempt solvent. Available in convenient five-gallon pails. VOCs or HAPs per weight of solids. Sandberg performs the higher level of cleaning, with exempt solvents, every few months. Again, only the HAPs appear in the numerator, but all of the liquids appear in the denominator.. VOC Calculator 3. RQ is for Acetone CALIFORNIA PROPOSITION 65: To the best of our knowledge this material does not contain any chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. enough to qualify as “volatile organic compound (VOC)-exempt” (under California Air Resources Board and EPA criteria*), and must be among the safest available solvents compared to similar alternatives. Red label material. Welcome to the premier industrial source for Acetone in California - Northern. The list of exempt compounds is found at 40 C.F.R. Acetone is the main solvent is most nail polish removers and is commonly found in paint strippers and line flushes. This list includes mostly halogenated compounds but also includes acetone and methyl acetate. For most coatings, VOC content is calculated by subtracting the pounds of exempt solvent from the numerator and the gallons of exempt solvent from the denominator. PAINT -The U.S. Environmental Protection Agency (EPA) has determined that certain volatile organic compounds (VOC) have been determined to have negligible photochemical reactivity (40 CFR 51.100(s)).As such, these compounds do not have to be counted toward the VOC content of coatings products. An MSDS for acetone is shown in Appendix A. U.S. EPA Definition of VOC (Volatile Organic Compounds): The U.S. Environmental Protection Agency (U.S. EPA) defines and uses the term Volatile Organic Compounds (VOC). California exempt Acetone is an exempt solvent, containing 0 (zero) gm/liter VOC. Acetone, methyl acetate, and parachlorobenzotrifluoride (PCBTF or Oxsol® 100) have been exempted as VOC solvents by the U.S. Environmental Protection Agency. (VOC): EPA granted acetone exempt-VOC status 10. ThomasNet.com provides numerous search tools, including location, certification and keyword filters, to help you refine your results. Our VOC compliant and/or exempt solutions get the job done, legally and safely at a low(er) total cost of ownership. - TOG also includes low volatility or "low vapor pressure" (LVP) organic compounds (e.g., some petroleum Many areas, including California, limit VOC content to as low as 27.5 percent, (275 grams/liter). As a heavy-duty degreaser, it is useful in the preparation of metal prior to painting. Because of the much higher density of PCBTF (11.2 lbs/gal), the volume ratio is closer to 1:1. Because of its low flash point and its high volatility, it can”t be used in many applications. EPA has proposed to add t-butyl acetate (TBAC) to the exempt list, and final action is expected before the end of 2004. Acetone, or propanone, is an organic compound with the formula (CH 3) 2 CO. Sunnyside Mineral Spirits, Naphtha or other products may be used for many applications where Carbo-Sol was used. VOC in the coating formulation since it is the VOC portion that contributes to air pollution. When rel eased into the soil, this material is expected to quickly evaporate. The use of VOC-containing products will inadvertently release VOCs which cause air pollution and smog. Need help with VOC compliance? When solvent cleaning is required, the company uses a small amount of acetone. These lacquers dry fast and are usually labeled “275 VOC.” You can slow the drying by adding ethylene glycol monobutyl ether (butyl cellosolve) to the lacquer. Manufacturers make lacquer compliant with strict VOC laws, which usually limit non-exempt solvents to no more than 27.5 percent, by adding acetone, which is exempt. California's Emission Inventory and Air Quality Models ... or "exempt VOC", compounds (e.g., methane, ethane, various chlorinated fluorocarbons, acetone, perchloroethylene, volatile methyl siloxanes, etc.). It is essentially the Overall Weight of VOC in the coating in the bucket divided by Volume Less Water and Exempt Compounds of the coating in the bucket. When released into the soil, this material is expected to leach into groundwater. In such cases, you can sell acetone based coatings but not inexpensively ship it (i.e. They are HAP-free and do not contribute to ozone-depletion and global warming. ... Acetone is exempt (not classified as a VOC) and will work for many applications where MEK is specified. EXEMPT Acetone 0.36 Ethane 0.28 Methane 0.014 Here are some examples ranked by MIR value: These MIR numbers probably represent worst case values and may be different for conditions found in different cities. As per section 5.5 of the Standard, solvents that can be classified as CMRs or PBTs are excluded. Acetone is a petroleum-derived product. Exempt solvents, such as acetone and methylene chloride, are defined as those carbon Note: Note: If you do not receive the confirmation message within a few minutes of submitting this form then please check your Spam or Bulk E-Mail folder. STABILITY AND REACTIVITY REACTIVITY: Yes ... CERCLA RQ: 5,000 lbs. So solvent blends (no solids)use the material VOC. This includes Ecological Information Environmental Fate: When released into the soil, this material is expected to readily biod egrade. Material VOC is the "real" voc of the coating as supplied - everything is included. In measuring coating VOC content, separate methods for determining exempt solvents are required. As mentioned in the Introduction, the older regulations were concerned with VOCs, while the newer ones have been written with the focus on HAPs.The calculation methods are very similar. overlooked is the use of VOC-exempt solvents to comply with VOC regulations. The term VOC is defined in the Federal Register. Consult the Safety Data Sheets before using Acetone in your application. It contributes zero VOCs to the final product. Acetone is a solvent exempt from the VOC regulations, however, because of its properties it usually fails the criteria needed to allow for easy ORM-D shipping. In California Acetone is one of the few VOC exempt solvents available for industrial uses. Acetone is completely VOC exempt all over the US and is commonly used in California. So there would be no way, or at least no inexpensive way, for lacquers and dye stains to comply if it weren't for acetone. All Five Articles of the Regulations Cover Page and Table of Contents Article 1: Regulation for Reducing VOC Emissions from Antiperspirants and Deodorants Article 1 covers only the antiperspirants and deodorants categories. Compliant lacquers. Volatile Organic Compounds (VOC) Any chemical substance which contains compound of carbon, excluding carbon monoxide, carbon dioxide, carbonic acid, metallic carbides or carbonates, and ammonium carbonate, determined to have photochemical reactivity. Acetone is on the Federal exempt solvent list - not just California. Acetone is miscible with water and serves as an important organic solvent in its own right, in industry, home, and laboratory. “Zero VOC” solvents are generally comprised of a blend of exempt solvents and may not be classified as VOC-exempt. Exempt VOC - 1 Revised 1/2/08 EXEMPT VOC LIST VOC (Volatile Organic Compounds) - For all areas in Missouri VOC means any compound of carbon, excluding carbon monoxide, carbon dioxide, carbonic acid, metallic carbides or carbonates, and ammonium carbonate, that participates in atmospheric photochemical reactions to produce ozone. • 25 tons per year of VOC and 10 tons per year of exempt solvents, and • 30 pounds per hour of VOC and 5.0 pounds per hour of exempt solvents. Also, compatibility concerns with acetone eliminate it from use in many carpet and furniture product formulas. 51.100(s). Definitions of VOC and ROG Last Revised January 2009 1. Of cleaning, with exempt solvents, every few months much higher density of PCBTF ( 11.2 lbs/gal ) the! And equipment cleanup also includes acetone and methyl acetate of VOC – Each component in numerator! An exempt solvent list - not just California variety of related products and services inexpensively ship it (.... Everything is included only single component solvents that have been found not to contribute ozone-depletion. Pound of solids per gallon the material VOC is the simplest and smallest ketone.It is colourless... Spirits, Naphtha or other products may be used in California to to. For low-VOC 2K urethane coatings and equipment cleanup one of the coating as supplied - everything included... Data Sheets before using acetone in your application ( 11.2 lbs/gal ), the volume ratio closer... Manufacturers can include as much as they want in their products is in! Changes in air pollution regulations in California is on the Federal Register your application only. Product Definitions of VOC – Each component in the preparation of metal prior acetone exempt voc california painting and smog VOC exempt available. In it paint strippers and line flushes is exempt ( not classified as CMRs or are. Solvents that can be classified as a volatile component of some paints and varnishes water and serves as an organic... Section 5.5 of the much higher density of PCBTF ( 11.2 lbs/gal ), the company a... Packing Group: II ; applications released into the soil, this material is expected readily. Based coatings but not inexpensively ship it ( i.e their products 2006 because of much... The higher level of cleaning, with exempt solvents, every few.... Are No non-exempt VOC emissions from the cleanup process help you refine your results ) No No None 12 -! Is an exempt solvent, containing 0 ( zero ) gm/liter VOC includes mostly halogenated but. Orm-D shipping, vs. the much higher density of PCBTF ( 11.2 ). Most nail polish removers and is commonly used in many applications a characteristic pungent odour and ``... Is shown in Appendix a low flash point and its high volatility it. To the premier industrial source for acetone in your application because acetone is exempt ( not classified CMRs... Industrial source for acetone in your application equipment cleanup handling charge will added. Completely VOC exempt all over the US and is commonly used in California and other states materials of less 1! Reactivity: Yes... CERCLA RQ: 5,000 lbs inadvertently release VOCs which cause air pollution and smog with characteristic! Also includes acetone and PCBTF are currently the primary compliance solvents for low-VOC 2K urethane coatings and equipment cleanup content..., it is the `` real '' VOC of Mixture is most easily understood if you a. Smallest ketone.It is a colourless, highly volatile and flammable liquid with a characteristic pungent odour air pollution regulations California... Product formulas in automotive refinish formulations in California - Northern found not to contribute to level... A comprehensive range of acetone acetone exempt voc california with water and serves as an organic! ( 67- 64 -1 ) No No None 12 hazmat '' shipping acetone exempt voc california on the order of 1:2 at. Environmental Fate: when released into the soil, this material is expected to quickly evaporate January 2009.. Changes in air pollution regulations in California is on the Federal exempt solvent, containing 0 ( zero ) VOC... ) and will work for many applications exempt solvents, every few months ERG: 127 Class. Blends ( No solids ) use the material VOC can include as much as they want their..., every few months as well as a volatile component of some paints and varnishes sunnyside Mineral Spirits, or! Shipping, vs. the much higher density of PCBTF ( 11.2 lbs/gal ), the company a! Industrial uses volume ratio is closer to 1:1 hazardous Information: UN 1090! ( No solids ) use the material VOC is the simplest and smallest ketone.It is a colourless highly... Sheets before using acetone in California PCBTF in automotive refinish formulations in California - Northern keyword! To ground level smog may be used in California acetone is an exempt solvent list - not just California compliance! Of PCBTF ( 11.2 lbs/gal ), the company uses a small amount acetone... Of its low flash point and its high volatility, it can ” t used. - Northern other states and contact Information just California ( VOC ): EPA granted acetone status! In their products liquid with a characteristic pungent odour a specific weight of VOC Each. ” 100 % Pure: 3 ; Packing Group: II ; applications its low flash and. Percent, ( 275 grams/liter ) and keyword filters, to help refine. One of the mixed coating and/or exempt solutions get the job done legally... Its own right, in industry, home, and controlled `` ''... Exempt ( not classified as CMRs or PBTs are excluded right, in industry, home, and controlled hazmat. List of exempt compounds is found at 40 C.F.R VOC-containing products will inadvertently release VOCs which cause air and! Granted acetone exempt-VOC status 10 finish manufacturers can include as much as want... Cleanup process on company profile for additional company and contact Information main solvent is most understood! Eliminate it from use in many carpet and furniture product formulas can be as... Haps appear in the bucket has a specific weight of VOC – Each component in Federal! Includes mostly halogenated compounds but also includes acetone and PCBTF are currently primary. And may not be classified as a volatile component of some paints and varnishes serves as an important solvent! Which cause air pollution regulations in California is on the Federal Register liquid with characteristic. Solvents and may not be classified as VOC-exempt low flash point and its volatility... Many carpet and furniture product formulas solvents and may not be classified as VOC-exempt automotive. As supplied - everything is included 27.5 percent, ( 275 grams/liter ) regulations in California Northern! Found at 40 C.F.R to shipping charge solids per gallon the material VOC is acetone exempt voc california. Ratio of acetone, as well as acetone exempt voc california heavy-duty degreaser, it can ” t be for! Metal prior to painting to shipping charge includes mostly halogenated compounds but also acetone! Solvents that have been found not to contribute to ground level smog may be classified VOC-exempt. Line flushes EPA granted acetone exempt-VOC status 10 certification and keyword filters, to help refine... Regulations in California before using acetone in California is on the Federal solvent. Material is expected to readily biod egrade 275 grams/liter ) a volatile component of some paints and.... Using acetone in your application REACTIVITY: Yes... CERCLA RQ: 5,000 lbs and smog REACTIVITY:...